Coligand Role in the NHC Nickel catalyzed C‒F Bond Activation: Investigations on the Insertion of bis(NHC) Nickel into the C‒F Bond of Hexafluorobenzene
Authors of publication
Kuntze-Fechner, Maximilian; Holthausen, Max C C.; Marder, Todd B.; Braunschweig, Holger; Krummenacher, Ivo; Radius, Udo; Tendera, Lukas; Verplancke, Hendrik; Diefenbach, Martin
Journal of publication
Chemical Science
Year of publication
2020
a
15.9816 ± 0.0012 Å
b
31.3 ± 0.002 Å
c
15.8502 ± 0.0012 Å
α
90°
β
90°
γ
90°
Cell volume
7928.7 ± 1 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
6
Space group number
52
Hermann-Mauguin space group symbol
P n n a
Hall space group symbol
-P 2a 2bc
Residual factor for all reflections
0.0759
Residual factor for significantly intense reflections
0.0528
Weighted residual factors for significantly intense reflections
0.1166
Weighted residual factors for all reflections included in the refinement
0.1267
Goodness-of-fit parameter for all reflections included in the refinement
