Information card for entry 1560040

Structure parameters

• Formula: C55 H66 N4 Ni Si2
• Calculated formula: C55 H66 N4 Ni Si2
• Title of publication: Boosting homogeneous chemoselective hydrogenation of olefins mediated by a bis(silylenyl)terphenyl-nickel(0) pre-catalyst
• Authors of publication: Lücke, Marcel-Philip; Yao, Shenglai; Driess, Matthias
• Journal of publication: Chemical Science
• Year of publication: 2021
• Journal volume: 12
• Journal issue: 8
• Pages of publication: 2909 - 2915
• a: 9.1662 ± 0.0005 Å
• b: 26.4418 ± 0.0013 Å
• c: 9.8935 ± 0.0006 Å
• α: 90°
• β: 90.567 ± 0.005°
• γ: 90°
• Cell volume: 2397.8 ± 0.2 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 0.1 K
• Number of distinct elements: 5
• Space group number: 11
• Hermann-Mauguin space group symbol: P 1 21/m 1
• Hall space group symbol: -P 2yb
• Residual factor for all reflections: 0.1221
• Residual factor for significantly intense reflections: 0.0982
• Weighted residual factors for significantly intense reflections: 0.2212
• Weighted residual factors for all reflections included in the refinement: 0.2417
• Goodness-of-fit parameter for all reflections included in the refinement: 1.194
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No