Information card for entry 1563347

Structure parameters

• Formula: C4 H6 Cs0 Eu2 Ge2 K8 Na4 O111 W22
• Calculated formula: C4 H6 Eu2 Ge2 K8 Na4 O111 W22
• SMILES: C1([O]2[Eu]345([O]=[W]678(O[W]9%10%11([O]%12%13[W]%14%15(=O)(O[W]%16%13(O9)(=O)O[W]9%13%17(O[W]%18%19(=O)(O[W]%20%21(O[W]%22(O6)(O[W]6(O[W](O%14)(O%18)([O]%13%19[Ge]%12([O]7[W](O9)(=O)(=[O]5)(O8)O%16)[O]%20%226)(=O)O%17)(=O)(O%15)O%21)(O%10)=O)(=[O]4)=O)=[O]3)=O)O%11)=O)=O)([OH2])([O]=1)[O]1C(C)=[O][Eu]34521([O]=[W]126(O[W]789([O]%10%11[W]%12%13(=O)(O[W]%14%11(O7)(=O)O[W]7%11%15(O[W]%16%17(=O)(O[W]%18%19(O[W]%20(O1)(O[W]1(O[W](O%12)(O%16)([O]%11%17[Ge]%10([O]2[W](O7)(=O)(=[O]5)(O6)O%14)[O]%18%201)(=O)O%15)(=O)(O%13)O%19)(O8)=O)(=[O]4)=O)=[O]3)=O)O9)=O)=O)[OH2])C.[K+].O.[K+].O.[K+].O.[K+].O.[Na+].[Na+].O.[Na+].O.O.O.O.O.O.O.O.O.[K+].O.[K+].O.[K+].O.[K+].O.[Na+].O.O.O.O.O.O.O.O.O
• Title of publication: A new series of lanthanoid containing Keggin-type germanotungstates with acetate chelators: [{Ln(CH3COO)GeW11O39(H2O)}2]12− {Ln=EuIII, GdIII, TbIII, DyIII, HoIII, ErIII, TmIII, and YbIII}
• Authors of publication: Hussain, Firasat; Sandriesser, Stefan; Speldrich, Manfred; Patzke, Greta R.
• Journal of publication: Journal of Solid State Chemistry
• Year of publication: 2011
• Journal volume: 184
• Journal issue: 1
• Pages of publication: 214 - 219
• a: 20.085 ± 0.003 Å
• b: 12.6741 ± 0.0009 Å
• c: 21.132 ± 0.003 Å
• α: 90°
• β: 110.983 ± 0.015°
• γ: 90°
• Cell volume: 5022.6 ± 1.2 ų
• Cell temperature: 183 ± 2 K
• Ambient diffraction temperature: 183 ± 2 K
• Number of distinct elements: 9
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1227
• Residual factor for significantly intense reflections: 0.0484
• Weighted residual factors for significantly intense reflections: 0.0665
• Weighted residual factors for all reflections included in the refinement: 0.0755
• Goodness-of-fit parameter for all reflections included in the refinement: 0.789
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No