Information card for entry 1567135

Structure parameters

• Chemical name: Ge9{Si(SiMe3)}3Rh(PMe3)
• Formula: C30 H90 Ge9 P Rh Si12
• Calculated formula: C30 H90 Ge9 P Rh Si12
• Title of publication: Zintl cluster supported low coordinate Rh(i) centers for catalytic H/D exchange between H2 and D2
• Authors of publication: Townrow, Oliver P. E.; Duckett, Simon B.; Weller, Andrew S.; Goicoechea, Jose M.
• Journal of publication: Chemical Science
• Year of publication: 2022
• a: 14.4411 ± 0.0001 Å
• b: 25.5519 ± 0.0002 Å
• c: 18.9046 ± 0.0001 Å
• α: 90°
• β: 101.771 ± 0.001°
• γ: 90°
• Cell volume: 6829.06 ± 0.08 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0456
• Residual factor for significantly intense reflections: 0.0393
• Weighted residual factors for significantly intense reflections: 0.0975
• Weighted residual factors for all reflections included in the refinement: 0.102
• Goodness-of-fit parameter for all reflections included in the refinement: 1.019
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No