Crystallography Open Database

Information card for entry 1567137

Preview

Coordinates	1567137.cif
Original paper (by DOI)	HTML

Structure parameters

Chemical name	Ge9{Si(SiMe3)}3Rh(Me2IMe)*hex
Formula	C40 H107 Ge9 N2 Rh Si12
Calculated formula	C40 H107 Ge9 N2 Rh Si12
Title of publication	Zintl cluster supported low coordinate Rh(i) centers for catalytic H/D exchange between H2 and D2
Authors of publication	Townrow, Oliver P. E.; Duckett, Simon B.; Weller, Andrew S.; Goicoechea, Jose M.
Journal of publication	Chemical Science
Year of publication	2022
a	16.3622 ± 0.0003 Å
b	19.8996 ± 0.0003 Å
c	25.9438 ± 0.0004 Å
α	68.56 ± 0.001°
β	79.856 ± 0.001°
γ	82.113 ± 0.001°
Cell volume	7715.4 ± 0.2 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 ± 2 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0593
Residual factor for significantly intense reflections	0.0544
Weighted residual factors for significantly intense reflections	0.1641
Weighted residual factors for all reflections included in the refinement	0.1728
Goodness-of-fit parameter for all reflections included in the refinement	1.048
Diffraction radiation wavelength	1.54184 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/1567137.html