Information card for entry 1568534

Structure parameters

• Formula: C22 H50 La N3 O Si5
• Calculated formula: C22 H50 La N3 O Si5
• Title of publication: Mechanistic study of homoleptic trisamidolanthanide-catalyzed aldehyde and ketone hydroboration. Chemically non-innocent ligand participation.
• Authors of publication: Rothbaum, Jacob O.; Motta, Alessandro; Kratish, Yosi; Marks, Tobin J.
• Journal of publication: Chemical science
• Year of publication: 2023
• Journal volume: 14
• Journal issue: 12
• Pages of publication: 3247 - 3256
• a: 21.1647 ± 0.0003 Å
• b: 15.1053 ± 0.0002 Å
• c: 21.1116 ± 0.0003 Å
• α: 90°
• β: 90.8294 ± 0.0013°
• γ: 90°
• Cell volume: 6748.65 ± 0.16 ų
• Cell temperature: 100 ± 0.2 K
• Ambient diffraction temperature: 100 ± 0.2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0562
• Residual factor for significantly intense reflections: 0.0372
• Weighted residual factors for significantly intense reflections: 0.0842
• Weighted residual factors for all reflections included in the refinement: 0.0934
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No