Information card for entry 1569946

Structure parameters

• Formula: C132 H306 Ce2 N32 O5 P8 Rb2
• Calculated formula: C132 H306 Ce2 N32 O5 P8 Rb2
• Title of publication: Structural distortion by alkali metal cations modulates the redox and electronic properties of Ce³⁺ imidophosphorane complexes.
• Authors of publication: Boggiano, Andrew C.; Studvick, Chad M.; Steiner, Alexander; Bacsa, John; Popov, Ivan A.; La Pierre, Henry S.
• Journal of publication: Chemical science
• Year of publication: 2023
• Journal volume: 14
• Journal issue: 42
• Pages of publication: 11708 - 11717
• a: 13.828 ± 0.001 Å
• b: 13.9994 ± 0.001 Å
• c: 23.9161 ± 0.0017 Å
• α: 95.768 ± 0.003°
• β: 105.731 ± 0.003°
• γ: 108.564 ± 0.003°
• Cell volume: 4135 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0987
• Residual factor for significantly intense reflections: 0.0856
• Weighted residual factors for significantly intense reflections: 0.2284
• Weighted residual factors for all reflections included in the refinement: 0.2432
• Goodness-of-fit parameter for all reflections included in the refinement: 1.094
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No