Information card for entry 1570977

Structure parameters

• Formula: C55 H88 Cl Ga N4 O Si
• Calculated formula: C55 H88 Cl Ga N4 O Si
• Title of publication: Catalytic hydroboration of aldehydes and ketones with an electron-rich acyclic metallasilylene.
• Authors of publication: Kapp, Leon; Wölper, Christoph; Siera, Hannah; Haberhauer, Gebhard; Schulz, Stephan
• Journal of publication: Chemical science
• Year of publication: 2024
• Journal volume: 15
• Journal issue: 11
• Pages of publication: 4161 - 4170
• a: 12.6656 ± 0.0007 Å
• b: 13.0233 ± 0.0007 Å
• c: 18.9626 ± 0.0011 Å
• α: 101.433 ± 0.003°
• β: 102.306 ± 0.003°
• γ: 111.151 ± 0.002°
• Cell volume: 2717.1 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0481
• Residual factor for significantly intense reflections: 0.0329
• Weighted residual factors for significantly intense reflections: 0.0803
• Weighted residual factors for all reflections included in the refinement: 0.088
• Goodness-of-fit parameter for all reflections included in the refinement: 1.043
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No