Information card for entry 1571051

Structure parameters

• Formula: C45 H78 Cs N Si2
• Calculated formula: C45 H78 Cs N Si2
• Title of publication: s-Block metal complexes of superbulky (^<i>t</i>Bu₃Si)₂N^-: a new weakly coordinating anion?
• Authors of publication: Knüpfer, Christian; Klerner, Lukas; Mai, Jonathan; Langer, Jens; Harder, Sjoerd
• Journal of publication: Chemical science
• Year of publication: 2024
• Journal volume: 15
• Journal issue: 12
• Pages of publication: 4386 - 4395
• a: 20.286 ± 0.0004 Å
• b: 14.13261 ± 0.00017 Å
• c: 17.3397 ± 0.0003 Å
• α: 90°
• β: 113.967 ± 0.002°
• γ: 90°
• Cell volume: 4542.57 ± 0.15 ų
• Cell temperature: 100.01 ± 0.1 K
• Ambient diffraction temperature: 100.01 ± 0.1 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0331
• Residual factor for significantly intense reflections: 0.0257
• Weighted residual factors for significantly intense reflections: 0.0568
• Weighted residual factors for all reflections included in the refinement: 0.0603
• Goodness-of-fit parameter for all reflections included in the refinement: 1.057
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No