Information card for entry 1571350

Structure parameters

• Formula: C102 H108 Ce O10 Si4
• Calculated formula: C94 H92 Ce O8 Si4
• Title of publication: Siloxide tripodal ligands as a scaffold for stabilizing lanthanides in the +4 oxidation state.
• Authors of publication: Tricoire, Maxime; Hsueh, Fang-Che; Keener, Megan; Rajeshkumar, Thayalan; Scopelliti, Rosario; Zivkovic, Ivica; Maron, Laurent; Mazzanti, Marinella
• Journal of publication: Chemical science
• Year of publication: 2024
• Journal volume: 15
• Journal issue: 18
• Pages of publication: 6874 - 6883
• a: 15.94855 ± 0.00011 Å
• b: 22.45159 ± 0.00016 Å
• c: 25.0337 ± 0.00019 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 8963.82 ± 0.11 ų
• Cell temperature: 139.99 ± 0.1 K
• Ambient diffraction temperature: 139.99 ± 0.1 K
• Number of distinct elements: 5
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0431
• Residual factor for significantly intense reflections: 0.0409
• Weighted residual factors for significantly intense reflections: 0.1073
• Weighted residual factors for all reflections included in the refinement: 0.1097
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No