Information card for entry 1571354

Structure parameters

• Formula: C88.5 H72 K O4 Si4 Tb
• Calculated formula: C85 H68 K O4 Si4 Tb
• Title of publication: Siloxide tripodal ligands as a scaffold for stabilizing lanthanides in the +4 oxidation state.
• Authors of publication: Tricoire, Maxime; Hsueh, Fang-Che; Keener, Megan; Rajeshkumar, Thayalan; Scopelliti, Rosario; Zivkovic, Ivica; Maron, Laurent; Mazzanti, Marinella
• Journal of publication: Chemical science
• Year of publication: 2024
• Journal volume: 15
• Journal issue: 18
• Pages of publication: 6874 - 6883
• a: 14.0838 ± 0.0014 Å
• b: 14.2282 ± 0.0017 Å
• c: 21.775 ± 0.003 Å
• α: 77.38 ± 0.01°
• β: 74.179 ± 0.009°
• γ: 63.234 ± 0.011°
• Cell volume: 3725 ± 0.9 ų
• Cell temperature: 200 ± 0.11 K
• Ambient diffraction temperature: 200 ± 0.11 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1308
• Residual factor for significantly intense reflections: 0.085
• Weighted residual factors for significantly intense reflections: 0.2142
• Weighted residual factors for all reflections included in the refinement: 0.2509
• Goodness-of-fit parameter for all reflections included in the refinement: 1.0844
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No