Information card for entry 1571994

Structure parameters

• Formula: C176 H426 Ag38 Co4 N26 O135 Si W9
• Calculated formula: C136 H206 Ag38 Co4 N6 O55 Si W9
• SMILES: [W]1234(O[W]567(O[W]89(O1)(O[W]1%10%11([O]%12%13[W]%14(O[W]%15%16%17([O]%18%19[W]%20(O%15)(O6)(=[O][Co]6%15%18([O]%18[Co]%21%22%23%12[O]%10[Ag]%10[O]%12%23[Ag]([O]%14%21)[C]%14([Ag][N]%21([Ag]%23[Ag]%21(ON(=O)=O)[C]%21([Ag][C]%24([Ag][C]%25%23[Ag]([C]%23([Ag][C]%26([Ag]%27[Ag]%26[Ag]%26%28[Ag]%29[C]%30%27[Ag]([C]%27%31[Ag][C]%32([Ag]%33[Ag]%34[C]%35%33[Ag]%33([C]#%35C(C)(C)C)[C]([Ag]%24)([Ag][C]([Ag][C]%24([Ag]%35[O]%36[W]%37(=O)([O]%38([W](O%37)(O7)(=O)(O%20)[O]7[Ag]%20[O]%37%35[Co]%35%36%387[O]%22[Co]%18([O]=C([O]%15[Ag]([Ag]%26)[C]([Ag](ON(=O)=O)[C]7([Ag]([C]%20([Ag]%15[C](#[C]%18%15[Ag]%32[Ag]%18(ON(=O)=O)[C]%34([Ag]%24)#CC(C)(C)C)C(C)(C)C)#CC(C)(C)C)[C]#7C(C)(C)C)[Ag]%27[C]#%31C(C)(C)C)([Ag][C]%28%29#CC(C)(C)C)#CC(C)(C)C)C)([O]6%35)([O]=C%12C)[O]=C%37C)[Si]%13%19[O]258)(O9)O%11)#CC(C)(C)C)([Ag][C]%10([Ag]%21)#CC(C)(C)C)#CC(C)(C)C)#[C]%33C(C)(C)C)#CC(C)(C)C)[C]#%30C(C)(C)C)#CC(C)(C)C)[Ag]([O]=%16)([C]#%23C(C)(C)C)[C]2([Ag](ON(=O)=O)[C]#2C(C)(C)C)[Ag]%14)[C]#%25C(C)(C)C)#CC(C)(C)C)#CC(C)(C)C)#CC)#CC(C)(C)C)[O]=%17)=O)O3)(O1)(O4)=O)=O)=O)=O)=O.CC#N
• Title of publication: Development of non-closed silver clusters by transition-metal-coordination-cluster substituted polyoxometalate templates.
• Authors of publication: Ge, Rui; Cai, Ping-Wei; Sun, Cai; Sun, Yan-Qiong; Li, Xin-Xiong; Zheng, Shou-Tian
• Journal of publication: Chemical science
• Year of publication: 2024
• Journal volume: 15
• Journal issue: 31
• Pages of publication: 12543 - 12549
• a: 21.95 ± 0.02 Å
• b: 23.43 ± 0.02 Å
• c: 30.98 ± 0.03 Å
• α: 105.088 ± 0.014°
• β: 94.144 ± 0.013°
• γ: 92.363 ± 0.014°
• Cell volume: 15313 ± 2 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1316
• Residual factor for significantly intense reflections: 0.0997
• Weighted residual factors for significantly intense reflections: 0.2225
• Weighted residual factors for all reflections included in the refinement: 0.2444
• Goodness-of-fit parameter for all reflections included in the refinement: 1.018
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No