Dinitrogen Reduction Chemistry with Scandium Provides a Complex with Two Side-on (N=N)2− Ligands Bound to One Metal: (C5Me5)Sc[(µ-η2:η2-N2)Sc(C5Me5)2]2
Authors of publication
Queen, Joshua D.; Rajabi, Ahmadreza; Goudzwaard, Quinn E.; Yuan, Qiong; Nguyen, Dang Khoa; Ziller, Joseph W.; Furche, Filipp; Xi, Zhenfeng; Evans, William J.
Journal of publication
Chemical Science
Year of publication
2024
a
43.206 ± 0.008 Å
b
9.8953 ± 0.0019 Å
c
25.757 ± 0.005 Å
α
90°
β
119.166 ± 0.003°
γ
90°
Cell volume
9616 ± 3 Å3
Cell temperature
183 ± 2 K
Ambient diffraction temperature
183 ± 2 K
Number of distinct elements
4
Space group number
15
Hermann-Mauguin space group symbol
C 1 2/c 1
Hall space group symbol
-C 2yc
Residual factor for all reflections
0.0802
Residual factor for significantly intense reflections
0.0446
Weighted residual factors for significantly intense reflections
0.1063
Weighted residual factors for all reflections included in the refinement
0.1226
Goodness-of-fit parameter for all reflections included in the refinement
