Dinitrogen Reduction Chemistry with Scandium Provides a Complex with Two Side-on (N=N)2− Ligands Bound to One Metal: (C5Me5)Sc[(µ-η2:η2-N2)Sc(C5Me5)2]2
Authors of publication
Queen, Joshua D.; Rajabi, Ahmadreza; Goudzwaard, Quinn E.; Yuan, Qiong; Nguyen, Dang Khoa; Ziller, Joseph W.; Furche, Filipp; Xi, Zhenfeng; Evans, William J.
Journal of publication
Chemical Science
Year of publication
2024
a
11.501 ± 0.0009 Å
b
11.579 ± 0.0009 Å
c
18.957 ± 0.0015 Å
α
82.26 ± 0.004°
β
81.73 ± 0.004°
γ
64.75 ± 0.003°
Cell volume
2252 ± 0.3 Å3
Cell temperature
93 ± 2 K
Ambient diffraction temperature
93 ± 2 K
Number of distinct elements
4
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0523
Residual factor for significantly intense reflections
0.0469
Weighted residual factors for significantly intense reflections
0.1163
Weighted residual factors for all reflections included in the refinement
0.1212
Goodness-of-fit parameter for all reflections included in the refinement
