Dinitrogen Reduction Chemistry with Scandium Provides a Complex with Two Side-on (N=N)2− Ligands Bound to One Metal: (C5Me5)Sc[(µ-η2:η2-N2)Sc(C5Me5)2]2
Authors of publication
Queen, Joshua D.; Rajabi, Ahmadreza; Goudzwaard, Quinn E.; Yuan, Qiong; Nguyen, Dang Khoa; Ziller, Joseph W.; Furche, Filipp; Xi, Zhenfeng; Evans, William J.
Journal of publication
Chemical Science
Year of publication
2024
a
10.9904 ± 0.0015 Å
b
11.3937 ± 0.0016 Å
c
14.908 ± 0.002 Å
α
90°
β
90°
γ
90°
Cell volume
1866.8 ± 0.4 Å3
Cell temperature
133 ± 2 K
Ambient diffraction temperature
133 ± 2 K
Number of distinct elements
4
Space group number
23
Hermann-Mauguin space group symbol
I 2 2 2
Hall space group symbol
I 2 2
Residual factor for all reflections
0.0563
Residual factor for significantly intense reflections
0.0458
Weighted residual factors for significantly intense reflections
0.1071
Weighted residual factors for all reflections included in the refinement
0.1123
Goodness-of-fit parameter for all reflections included in the refinement