Reversible C–C bond formation in group 4 metal complexes: nitrile extrusion via β-aryl elimination
Authors of publication
Kulyabin, Pavel S.; Goryunov, Georgy P.; Iashin, Andrei N.; Mladentsev, Dmitry Y.; Uborsky, Dmitry V.; Ehm, Christian; Canich, Jo Ann M.; Hagadorn, John R.; Voskoboynikov, Alexander Z.
Journal of publication
Chemical Science
Year of publication
2024
a
9.488 ± 0.0003 Å
b
38.1993 ± 0.0014 Å
c
9.6016 ± 0.0003 Å
α
90°
β
114.088 ± 0.001°
γ
90°
Cell volume
3176.92 ± 0.18 Å3
Cell temperature
120 K
Ambient diffraction temperature
120 K
Number of distinct elements
5
Space group number
4
Hermann-Mauguin space group symbol
P 1 21 1
Hall space group symbol
P 2yb
Residual factor for all reflections
0.0524
Residual factor for significantly intense reflections
0.0469
Weighted residual factors for significantly intense reflections
0.0903
Weighted residual factors for all reflections included in the refinement
0.0932
Goodness-of-fit parameter for all reflections included in the refinement