Reversible C–C bond formation in group 4 metal complexes: nitrile extrusion via β-aryl elimination
Authors of publication
Kulyabin, Pavel S.; Goryunov, Georgy P.; Iashin, Andrei N.; Mladentsev, Dmitry Y.; Uborsky, Dmitry V.; Ehm, Christian; Canich, Jo Ann M.; Hagadorn, John R.; Voskoboynikov, Alexander Z.
Journal of publication
Chemical Science
Year of publication
2024
a
44.5128 ± 0.0008 Å
b
44.5128 ± 0.0008 Å
c
9.3817 ± 0.0003 Å
α
90°
β
90°
γ
120°
Cell volume
16098.4 ± 0.7 Å3
Cell temperature
120 K
Ambient diffraction temperature
120 K
Number of distinct elements
5
Space group number
148
Hermann-Mauguin space group symbol
R -3 :H
Hall space group symbol
-R 3
Residual factor for all reflections
0.053
Residual factor for significantly intense reflections
0.0406
Weighted residual factors for significantly intense reflections
0.0814
Weighted residual factors for all reflections included in the refinement
0.0872
Goodness-of-fit parameter for all reflections included in the refinement