Information card for entry 1573816

Structure parameters

• Formula: C109 H108 Cl2 N8 Pd6 Si2
• Calculated formula: C109 H108 Cl2 N8 Pd6 Si2
• Title of publication: A coordination polymer with a silylene-supported Pd₆ core as an efficient heterogeneous hydrogenation catalyst.
• Authors of publication: Mitomo, Taiga; Wada, Yoshimasa; Suda, Tetsuro; Tamura, Atsushi; Yagi, Shunsuke; Kikkawa, Soichi; Yamazoe, Seiji; Sunada, Yusuke
• Journal of publication: Chemical science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 10
• Pages of publication: 4450 - 4455
• a: 16.1964 ± 0.0008 Å
• b: 18.6192 ± 0.0011 Å
• c: 18.8234 ± 0.0011 Å
• α: 83.984 ± 0.005°
• β: 80.702 ± 0.004°
• γ: 73.139 ± 0.005°
• Cell volume: 5351 ± 0.5 ų
• Cell temperature: 123 K
• Ambient diffraction temperature: 123 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.274
• Residual factor for significantly intense reflections: 0.0869
• Weighted residual factors for significantly intense reflections: 0.1433
• Weighted residual factors for all reflections included in the refinement: 0.2086
• Goodness-of-fit parameter for all reflections included in the refinement: 0.942
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No