Information card for entry 1574643

Structure parameters

• Formula: C72 H169 Ag20 O24 P12 Rh Se24
• Calculated formula: C72 H169 Ag20 O24 P12 Rh Se24
• SMILES: C(C)(C)OP1(OC(C)C)=[Se][Ag]234[Ag]567[Ag]89%10%11[Ag]%12%13%14([Ag])[Ag]%15%16%17[Ag]%18%19[Ag]%20%21([Ag]%15([Se]1)[Se]=P(OC(C)C)(OC(C)C)[Se]%13)([RhH]18%12[Ag]8%12%135[Ag]5([Ag]9%14[Ag]9%18([Se]=P(OC(C)C)(OC(C)C)[Se][Ag]%14%15%18[Ag]%22%23%19%21[Ag]3%20[Ag]%15([Ag]71%12([Ag]%139%14%22)[Se]=P(OC(C)C)(OC(C)C)[Se]%18)([Se]=P(OC(C)C)(OC(C)C)[Se]4)[Se]=P(OC(C)C)(OC(C)C)[Se]%23)([Se]=P([Se]%17)(OC(C)C)OC(C)C)[Se]=P(OC(C)C)(OC(C)C)[Se]5)([Ag]6%10([Se]=P(OC(C)C)(OC(C)C)[Se]2)[Se]=P(OC(C)C)(OC(C)C)[Se]8)[Se]=P(OC(C)C)(OC(C)C)[Se]%11)[Se]=P(OC(C)C)(OC(C)C)[Se]%16
• Title of publication: Rhodium-silver superatomic nanoclusters stabilized by diselenophosphate ligands.
• Authors of publication: Chiu, Tzu-Hao; Pillay, Michael N.; Kahlal, Samia; Saillard, Jean-Yves; Liu, C. W.
• Journal of publication: Nanoscale
• Year of publication: 2025
• Journal volume: 17
• Journal issue: 21
• Pages of publication: 13502 - 13509
• a: 32.578 ± 0.002 Å
• b: 32.578 ± 0.002 Å
• c: 32.578 ± 0.002 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 34576 ± 4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 197
• Hermann-Mauguin space group symbol: I 2 3
• Hall space group symbol: I 2 2 3
• Residual factor for all reflections: 0.0906
• Residual factor for significantly intense reflections: 0.0592
• Weighted residual factors for significantly intense reflections: 0.1234
• Weighted residual factors for all reflections included in the refinement: 0.1469
• Goodness-of-fit parameter for all reflections included in the refinement: 1.078
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No