Information card for entry 1575974

Structure parameters

• Common name: Rh5
• Formula: C29 H40 Cl4 N3 O3 Rh Si
• Calculated formula: C29 H40 Cl4 N3 O3 Rh Si
• Title of publication: Confinement-induced Z-selectivity in the rhodium N-heterocyclic carbene-catalyzed hydroboration of terminal alkynes
• Authors of publication: Atwi, Boshra; Wang, Dongren; Bruckner, Johanna R.; Frey, Wolfgang; Buchmeiser, Michael R.
• Journal of publication: Catalysis Science & Technology
• Year of publication: 2025
• Journal volume: 15
• Journal issue: 23
• Pages of publication: 7059 - 7066
• a: 7.1511 ± 0.0004 Å
• b: 18.5598 ± 0.0014 Å
• c: 24.6117 ± 0.0018 Å
• α: 90°
• β: 94.408 ± 0.003°
• γ: 90°
• Cell volume: 3256.9 ± 0.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1321
• Residual factor for significantly intense reflections: 0.0586
• Weighted residual factors for significantly intense reflections: 0.1031
• Weighted residual factors for all reflections included in the refinement: 0.1217
• Goodness-of-fit parameter for all reflections included in the refinement: 1.024
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No