Information card for entry 2000570

Structure parameters

• Chemical name: tetrakis(μ-methyldiphenylsilanecarboxylato-O,O')bis(triphenylphosphine) dinickel
• Formula: C92 H82 Ni2 O8 P2 Si4
• Calculated formula: C92 H82 Ni2 O8 P2 Si4
• SMILES: [P](c1ccccc1)(c1ccccc1)([Ni]1234[O]=C([Si](C)(c5ccccc5)c5ccccc5)O[Ni]4([P](c4ccccc4)(c4ccccc4)c4ccccc4)([O]=C(O1)[Si](C)(c1ccccc1)c1ccccc1)([O]=C(O3)[Si](C)(c1ccccc1)c1ccccc1)OC(=[O]2)[Si](C)(c1ccccc1)c1ccccc1)c1ccccc1
• Title of publication: Dimeric nickel(II) carboxylates and a silanecarboxylate: [Ni(Me~3~CCOO)~2~(2,5-lutidine)]~2~, [Ni(MePh~2~CCOO)~2~(quinoline)]~2~.2CHCl~3~, [Ni(Me~2~PhCCOO)~2~(quinoline)]~2~, [Ni(Me~3~CCOO)~2~(2-ethylpyridine)]~2~, [Ni(Me~3~CCOO)~2~(2-picoline)]~2~ and [Ni(MePh~2~SiCOO)~2~(Ph~3~P)]~2~
• Authors of publication: Morooka, M.; Ohba, S.; Nakashima, M.; Tokii, T.; Muto, Y.; Kato, M.; Steward, O. W.
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 1992
• Journal volume: 48
• Journal issue: 10
• Pages of publication: 1888 - 1894
• a: 14.461 ± 0.001 Å
• b: 23.432 ± 0.001 Å
• c: 13.542 ± 0.001 Å
• α: 90°
• β: 112.921 ± 0.004°
• γ: 90°
• Cell volume: 4226.4 ± 0.5 ų
• Cell temperature: 299 K
• Ambient diffraction temperature: 299 ± 1 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for significantly intense reflections: 0.044
• Weighted residual factors for significantly intense reflections: 0.035
• Goodness-of-fit parameter for significantly intense reflections: 2.666
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No