Information card for entry 2001620

Structure parameters

• Chemical name: (2,4-Pentanedionato-O,O')bis(phenyl 3,3',5,5'-tetra-tert-butyl-1,1'-biphenyl-2,2'-diyl phosphite-P)rhodium
• Formula: C87 H113 O8 P2 Rh
• Calculated formula: C80 H105 O8 P2 Rh
• Title of publication: Structure of (2,4-pentanedionato-<i>O</i>,<i>O</i>')bis(phenyl 3,3',5,5'-tetra-<i>tert</i>-butyl-1,1'-biphenyl-2,2'-diyl phosphite-<i>P</i>)rhodium
• Authors of publication: Meetsma, A.; Jongsma, T.; Challa, G.; van Leeuwen, P. W. N. M.
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 1993
• Journal volume: 49
• Journal issue: 6
• Pages of publication: 1160 - 1163
• a: 11.624 ± 0.001 Å
• b: 17.244 ± 0.002 Å
• c: 18.877 ± 0.001 Å
• α: 79.884 ± 0.008°
• β: 84.812 ± 0.006°
• γ: 75.398 ± 0.009°
• Cell volume: 3600.4 ± 0.6 ų
• Cell temperature: 130 K
• Ambient diffraction temperature: 130 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.042
• Weighted residual factors for all reflections: 0.046
• Weighted residual factors for significantly intense reflections: 0.046
• Goodness-of-fit parameter for significantly intense reflections: 1.842
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No