Information card for entry 2003075

Structure parameters

• Chemical name: Tetrakis(2,2'-bipyridine)bis(mu-oxo)dimanganese(3+) hexanitratocerate(3-) pentahydrate
• Formula: C40 H42 Ce Mn2 N14 O25
• Calculated formula: C40 H42 Ce Mn2 N14 O25
• Title of publication: Crystallographic disorder in mixed-valent dioxo-bridged Mn^III,IV^ complexes. [Mn~2~O~2~(bpy)~4~][Ce(NO~3~)~6~].5H~2~O
• Authors of publication: D. Ramalakshmi; M. V. Rajasekharan
• Journal of publication: Acta Crystallographica Section B
• Year of publication: 1999
• Journal volume: 55
• Journal issue: 2
• Pages of publication: 186 - 191
• a: 12.94 ± 0.003 Å
• b: 18.06 ± 0.002 Å
• c: 22.544 ± 0.011 Å
• α: 90°
• β: 96.29 ± 0.02°
• γ: 90°
• Cell volume: 5237 ± 3 ų
• Cell temperature: 132 ± 2 K
• Ambient diffraction temperature: 132 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0539
• Residual factor for significantly intense reflections: 0.0358
• Weighted residual factors for all reflections: 0.0947
• Weighted residual factors for significantly intense reflections: 0.0783
• Goodness-of-fit parameter for all reflections: 1.105
• Goodness-of-fit parameter for significantly intense reflections: 1.136
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No