Information card for entry 2004977

Structure parameters

• Common name: [NBDRh(II-phophos)~2~](BF~4~)~3~
• Chemical name: Bis{2-(diphenylphosphinoethyl)trimethylphosphonium}(norbornadiene)rhodium(I) Fluoroborate
• Formula: C43 H58 B3 F12 P4 Rh
• Calculated formula: C43 H58 B3 F12.003 P4 Rh
• Title of publication: Bis{[3-(diphenylphosphino)propyl]trimethylphosphonium-<i>P</i>}[(2,3,5,6-η)-norbornadiene]rhodium(I) Tris(tetrafluoroborate)
• Authors of publication: Roszak, A. W.; Renaud, E.; Baird, M. C.
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 1996
• Journal volume: 52
• Journal issue: 6
• Pages of publication: 1359 - 1362
• a: 14.021 ± 0.002 Å
• b: 15.613 ± 0.002 Å
• c: 15.43 ± 0.002 Å
• α: 116.34 ± 0.01°
• β: 124.84 ± 0.01°
• γ: 75.36 ± 0.01°
• Cell volume: 2484.5 ± 0.7 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0962
• Residual factor for significantly intense reflections: 0.0495
• Weighted residual factors for all reflections: 0.1591
• Weighted residual factors for significantly intense reflections: 0.1228
• Goodness-of-fit parameter for all reflections: 1.112
• Goodness-of-fit parameter for significantly intense reflections: 1.155
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No