Information card for entry 2006031

Structure parameters

• Formula: C23 H38 Cl N3 Si2 W
• Calculated formula: C23 H38 Cl N3 Si2 W
• SMILES: [W]1(Cl)(N([Si](C)(C)C)c2ccccc2N1[Si](C)(C)C)(=Nc1ccccc1)CC(C)(C)C
• Title of publication: A Chelate-Stabilized Tungsten‒Imido‒Monoalkyl Complex, [WCl(PhN)(CH~2~CMe~3~){<i>o</i>-C~6~H~4~(NSiMe~3~)~2~}]
• Authors of publication: Wang, S.-Y. S.; Boncella, J. M.; Abboud, K. A.
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 1997
• Journal volume: 53
• Journal issue: 4
• Pages of publication: 436 - 438
• a: 9.3531 ± 0.0001 Å
• b: 11.264 ± 0.0002 Å
• c: 14.1166 ± 0.0002 Å
• α: 96.705 ± 0.001°
• β: 93.814 ± 0.001°
• γ: 111.296 ± 0.001°
• Cell volume: 1366.63 ± 0.04 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0376
• Residual factor for significantly intense reflections: 0.034
• Weighted residual factors for all reflections: 0.091
• Weighted residual factors for significantly intense reflections: 0.085
• Goodness-of-fit parameter for all reflections: 1.08
• Goodness-of-fit parameter for significantly intense reflections: 1.068
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No