Information card for entry 2008477

Structure parameters

• Chemical name: tetrakis(trimethylphosphine)rhodium(I) bis(catecholato)borate
• Formula: C24 H44 B O4 P4 Rh
• Calculated formula: C24 H44 B O4 P4 Rh
• SMILES: [Rh]([P](C)(C)C)([P](C)(C)C)([P](C)(C)C)[P](C)(C)C.[B-]12(Oc3c(O1)cccc3)Oc1c(O2)cccc1
• Title of publication: Salts of the bis(catecholato)borate anion with rhodium‒ and iridium‒phosphine complex cations
• Authors of publication: Clegg, William; Elsegood, Mark R.J.; Scott, Andrew J.; Marder, Todd B.; Dai, Chaoyang; Norman, Nicholas C.; Pickett, Nigel L.; Robins, Edward G.
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 1999
• Journal volume: 55
• Journal issue: 5
• Pages of publication: 733 - 739
• a: 9.7315 ± 0.0009 Å
• b: 29.559 ± 0.003 Å
• c: 10.8716 ± 0.001 Å
• α: 90°
• β: 102.541 ± 0.002°
• γ: 90°
• Cell volume: 3052.6 ± 0.5 ų
• Cell temperature: 160 ± 2 K
• Ambient diffraction temperature: 160 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0609
• Residual factor for significantly intense reflections: 0.0365
• Weighted residual factors for all reflections included in the refinement: 0.0815
• Goodness-of-fit parameter for all reflections included in the refinement: 1.053
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No