Information card for entry 2009888

Structure parameters

• Chemical name: tris(μ-chloro)-bis[1,1,1-tris(diphenylphosphinomethyl)ethane- P, P', P'']dirhodium(III) trifluoromethanesulfonate
• Formula: C85 H78 Cl3 F9 O9 P6 Rh2 S3
• Calculated formula: C85 H78 Cl3 F9 O9 P6 Rh2 S3
• Title of publication: A tri-μ-chloro dirhodium (III) complex [Rh~2~(μ-Cl)~3~(triphos)~2~](CF~3~SO~3~)~3~ [triphos = CH~3~C(CH~2~PPh~2~)~3~]
• Authors of publication: Bachechi, Fiorella
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 1994
• Journal volume: 50
• Journal issue: 7
• Pages of publication: 1069 - 1072
• a: 26.43 ± 0.006 Å
• b: 26.43 ± 0.006 Å
• c: 26.43 ± 0.006 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 18463 ± 7 ų
• Cell temperature: 295 K
• Ambient diffraction temperature: 298 K
• Number of distinct elements: 8
• Hermann-Mauguin space group symbol: P a -3
• Hall space group symbol: -P 2ac 2ab 3
• Residual factor for significantly intense reflections: 0.068
• Weighted residual factors for significantly intense reflections: 0.0759
• Goodness-of-fit parameter for significantly intense reflections: 4.12
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No