Information card for entry 2012096

Structure parameters

• Chemical name: bis-(octacarbonyl-μ-dicyclohexylphosphido-dirhenium)- dicarbonyl-platinum
• Formula: C42 H44 O18 P2 Pt Re4
• Calculated formula: C42 H44 O18 P2 Pt Re4
• SMILES: [Pt]1([Re]([P]([Re]1(C#[O])(C#[O])(C#[O])C#[O])(C1CCCCC1)C1CCCCC1)(C#[O])(C#[O])(C#[O])C#[O])([Re]([P]([Re](C#[O])(C#[O])(C#[O])C#[O])(C1CCCCC1)C1CCCCC1)(C#[O])(C#[O])(C#[O])C#[O])(C#[O])C#[O]
• Title of publication: A pseudo-trigonal bipyramidally coordinated Pt atom in dicarbonylbis(octacarbonyl-μ-dicyclohexylphosphidodirhenio)platinum(II)
• Authors of publication: Haupt, Hans-Jürgen; Flörke, Ulrich; Klose, Stefanie
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2001
• Journal volume: 57
• Journal issue: 7
• Pages of publication: 810 - 811
• a: 17.561 ± 0.002 Å
• b: 16.728 ± 0.003 Å
• c: 17.408 ± 0.006 Å
• α: 90°
• β: 102.42 ± 0.02°
• γ: 90°
• Cell volume: 4994 ± 2 ų
• Cell temperature: 203 ± 2 K
• Ambient diffraction temperature: 203 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1606
• Residual factor for significantly intense reflections: 0.0592
• Weighted residual factors for all reflections included in the refinement: 0.1698
• Goodness-of-fit parameter for all reflections included in the refinement: 0.974
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes