Information card for entry 2012955

Structure parameters

• Chemical name: Bis(trichlorophosphino)iminium tri-μ-chloro-bis[trichlorotitanium(IV)]
• Formula: Cl15 N P2 Ti2
• Calculated formula: Cl15 N P2 Ti2
• Title of publication: Bis(trichlorophosphine)iminium salts, [Cl~3~P=N=PCl~3~]^+^, with transition metal halide counter-ions
• Authors of publication: Rivard, Eric; McWilliams, Andrew R.; Lough, Alan J.; Manners, Ian
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2002
• Journal volume: 58
• Journal issue: 9
• Pages of publication: i114 - i118
• a: 8.9436 ± 0.0004 Å
• b: 9.0892 ± 0.0004 Å
• c: 14.2963 ± 0.0006 Å
• α: 91.77 ± 0.002°
• β: 105.714 ± 0.003°
• γ: 107.973 ± 0.002°
• Cell volume: 1055.78 ± 0.08 ų
• Cell temperature: 250 ± 1 K
• Ambient diffraction temperature: 250 ± 1 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.051
• Residual factor for significantly intense reflections: 0.0363
• Weighted residual factors for significantly intense reflections: 0.0923
• Weighted residual factors for all reflections included in the refinement: 0.0989
• Goodness-of-fit parameter for all reflections included in the refinement: 1.024
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: Yes