Information card for entry 2014055

Structure parameters

• Chemical name: μ-ethane-1,2-diylbis(diphenylphosphine oxide)-κ^2^O:O'- bis[dibenzyldichlorotin(IV)]
• Formula: C54 H52 Cl4 O2 P2 Sn2
• Calculated formula: C54 H52 Cl4 O2 P2 Sn2
• SMILES: C(P(=[O][Sn](Cc1ccccc1)(Cc1ccccc1)(Cl)Cl)(c1ccccc1)c1ccccc1)CP(=[O][Sn](Cc1ccccc1)(Cc1ccccc1)(Cl)Cl)(c1ccccc1)c1ccccc1
• Title of publication: μ-Ethane-1,2-diylbis(diphenylphosphine oxide)-κ^2^<i>O</i>:<i>O</i>'-bis[dibenzyldichlorotin(IV)]: a centrosymmetric complex containing trigonal-bipyramidal tin(IV), linked into chains of rings by C—H···π(arene) hydrogen bonds
• Authors of publication: Mohamed, E. Mothi; Panchanatheswaran, Krishnaswamy; Low, John N.; Glidewell, Christopher
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2004
• Journal volume: 60
• Journal issue: 4
• Pages of publication: m172 - m173
• a: 15.01 ± 0.0005 Å
• b: 14.7055 ± 0.0006 Å
• c: 22.6909 ± 0.0006 Å
• α: 90°
• β: 91.571 ± 0.002°
• γ: 90°
• Cell volume: 5006.7 ± 0.3 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0841
• Residual factor for significantly intense reflections: 0.0399
• Weighted residual factors for significantly intense reflections: 0.0718
• Weighted residual factors for all reflections included in the refinement: 0.083
• Goodness-of-fit parameter for all reflections included in the refinement: 0.959
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes