Information card for entry 2015023

Structure parameters

• Chemical name: bis[μ-N,N'-bis(3-methoxysalicylidene)ethylenediaminato- κ^5^O,N,N',O':O]bis[(methanol-κO)manganese(III)] diperchlorate
• Formula: C38 H44 Cl2 Mn2 N4 O18
• Calculated formula: C38 H44 Cl2 Mn2 N4 O18
• Title of publication: Diaqua[<i>N</i>,<i>N</i>'-bis(5-methoxysalicylidene)ethylenediaminato-κ^4^<i>O</i>,<i>N</i>,<i>N</i>',<i>O</i>']manganese(III) perchlorate, aqua[<i>N</i>,<i>N</i>'-bis(3,5-dichlorosalicylidene)ethylenediaminato-κ^4^<i>O</i>,<i>N</i>,<i>N</i>',<i>O</i>'](methanol-κ<i>O</i>)manganese(III) perchlorate and bis[μ-<i>N</i>,<i>N</i>'-bis(3-methoxysalicylidene)ethylenediaminato-κ^5^<i>O</i>,<i>N</i>,<i>N</i>',<i>O</i>':<i>O</i>]bis[(methanol-κ<i>O</i>)manganese(III)] diperchlorate
• Authors of publication: Akitsu, Takashiro; Takeuchi, Yuiri; Einaga, Yasuaki
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2005
• Journal volume: 61
• Journal issue: 7
• Pages of publication: m324 - m328
• a: 15.226 ± 0.006 Å
• b: 13.026 ± 0.004 Å
• c: 10.865 ± 0.004 Å
• α: 90°
• β: 99.58 ± 0.03°
• γ: 90°
• Cell volume: 2124.8 ± 1.3 ų
• Cell temperature: 297 ± 2 K
• Ambient diffraction temperature: 297 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0413
• Residual factor for significantly intense reflections: 0.0345
• Weighted residual factors for significantly intense reflections: 0.0962
• Weighted residual factors for all reflections included in the refinement: 0.1011
• Goodness-of-fit parameter for all reflections included in the refinement: 1.041
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No