Information card for entry 2015223

Structure parameters

• Chemical name: Tris(cyclohexane-1,2-diamine-κ^2^N,N')cobalt pentachloroplumbate sesquihydrate, [Co(C~6~H~14~N~2~)~3~][PbCl~5~].1.5H~2~O
• Formula: C18 H45 Cl5 Co N6 O1.5 Pb
• Calculated formula: C18 H45 Cl5 Co N6 O1.5 Pb
• SMILES: [Co]123([NH2][C@H]4[C@H]([NH2]1)CCCC4)([NH2][C@H]1[C@H]([NH2]2)CCCC1)[NH2][C@H]1[C@H]([NH2]3)CCCC1.[Pb](Cl)(Cl)([Cl-])([Cl-])[Cl-].O.O.[Co]123([NH2][C@@H]4[C@@H]([NH2]1)CCCC4)([NH2][C@@H]1[C@@H]([NH2]2)CCCC1)[NH2][C@@H]1[C@@H]([NH2]3)CCCC1.[Pb](Cl)(Cl)([Cl-])([Cl-])[Cl-].O.O
• Title of publication: The first salt of an isolated pentachloroplumbate(II) trianion
• Authors of publication: Kalf, Irmgard; Englert, Ulli
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2006
• Journal volume: 62
• Journal issue: 4
• Pages of publication: m129 - m131
• a: 27.066 ± 0.002 Å
• b: 12.4657 ± 0.0011 Å
• c: 21.3066 ± 0.0019 Å
• α: 90°
• β: 125.889 ± 0.001°
• γ: 90°
• Cell volume: 5824 ± 0.9 ų
• Cell temperature: 110 ± 2 K
• Ambient diffraction temperature: 110 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0335
• Residual factor for significantly intense reflections: 0.0263
• Weighted residual factors for significantly intense reflections: 0.047
• Weighted residual factors for all reflections included in the refinement: 0.0479
• Goodness-of-fit parameter for all reflections included in the refinement: 1.013
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes