Information card for entry 2015417

Structure parameters

• Chemical name: diaquatetra-μ-acetamidato-κ^4^N:O;κ^4^O:N-dirhodium(II,III) hexafluorophosphate dihydrate
• Formula: C8 H24 F6 N4 O8 P Rh2
• Calculated formula: C8 H24 F6 N4 O8 P Rh2
• SMILES: C1(C)N[Rh]234(NC(=[O][Rh]4([O]=1)(NC(C)=[O]2)(NC(C)=[O]3)[OH2])C)[OH2].[P](F)(F)(F)(F)(F)[F-].O.O
• Title of publication: Variation of hydrogen-bonded networks in hexafluorophosphate salts of amidate-bridged dirhodium(II,III) complexes with axial aqua ligands
• Authors of publication: Ebihara, Masahiro; Fuma, Yasuhiro
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2006
• Journal volume: 62
• Journal issue: 7
• Pages of publication: m284 - m289
• a: 11.69 ± 0.0017 Å
• b: 11.57 ± 0.0013 Å
• c: 7.98 ± 0.0013 Å
• α: 90°
• β: 110.51 ± 0.006°
• γ: 90°
• Cell volume: 1010.9 ± 0.3 ų
• Cell temperature: 118 ± 2 K
• Ambient diffraction temperature: 118 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.03
• Residual factor for significantly intense reflections: 0.0265
• Weighted residual factors for significantly intense reflections: 0.0547
• Weighted residual factors for all reflections included in the refinement: 0.0558
• Goodness-of-fit parameter for all reflections included in the refinement: 1.172
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes