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Information card for entry 2017695
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Coordinates | 2017695.cif |
---|---|
Structure factors | 2017695.hkl |
Original IUCr paper | HTML |
Common name | (salen)chromium(V)-(μ-nitrido)-chloro(COD)rhodium(I) |
---|---|
Chemical name | chlorido-2κ<i>Cl</i>-[2(η^4^)-1,5-cyclooctadiene]{2,2'-[ethane-1,2- diylbis(nitrilomethylidyne)]diphenolato- 1κ^4^<i>O</i>,<i>N</i>,<i>N</i>',<i>O</i>'}-μ-nitrido- 1:2κ^2^<i>N</i>:<i>N</i>-chromium(V)rhodium(I) |
Formula | C24 H26 Cl Cr N3 O2 Rh |
Calculated formula | C24 H26 Cl Cr N3 O2 Rh |
SMILES | [Rh]123(Cl)(N=[Cr]456[N](=Cc7c(O5)cccc7)CC[N]4=Cc4ccccc4O6)[CH]4CC[CH]1=[CH]2CC[CH]3=4 |
Title of publication | Synthesis and molecular structure of Cr(salen)(μ-N)RhCl(COD): the first example of a heterobimetallic nitride-bridged complex containing chromium |
Authors of publication | Vibenholt, Johan; Magnussen, Magnus; Anthon, Christian; Bendix, Jesper |
Journal of publication | Acta Crystallographica Section C |
Year of publication | 2010 |
Journal volume | 66 |
Journal issue | 7 |
Pages of publication | m177 - m179 |
a | 12.614 ± 0.0013 Å |
b | 15.1085 ± 0.0014 Å |
c | 12.6704 ± 0.0017 Å |
α | 90° |
β | 107.259 ± 0.01° |
γ | 90° |
Cell volume | 2306 ± 0.5 Å3 |
Cell temperature | 122 ± 1 K |
Ambient diffraction temperature | 122 ± 1 K |
Number of distinct elements | 7 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for all reflections | 0.0458 |
Residual factor for significantly intense reflections | 0.0294 |
Weighted residual factors for significantly intense reflections | 0.0607 |
Weighted residual factors for all reflections included in the refinement | 0.0667 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.064 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | Yes |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/2017695.html
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