Information card for entry 2018800

Structure parameters

• Chemical name: <i>catena</i>-Poly[[[bis(ethane-1,2-diamine- κ^2^<i>N</i>,<i>N</i>')platinum(II)]-μ-thiocyanato-κ^2^<i>S</i>:<i>S</i>- [bis(ethane-1,2-diamine-κ^2^<i>N</i>,<i>N</i>')platinum(IV)]-μ- thiocyanato-κ^2^<i>S</i>:<i>S</i>] tetrakis(perchlorate)]
• Formula: C10 H32 Cl4 N10 O16 Pt2 S2
• Calculated formula: C10 H32 Cl4 N10 O16 Pt2 S2
• SMILES: C(#N)S[Pt]12([NH2]CC[NH2]1)([NH2]CC[NH2]2)SC#N.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Pt]12([NH2]CC[NH2]1)[NH2]CC[NH2]2.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
• Title of publication: A one-dimensional platinum mixed-valence complex with bridging thiocyanate S atoms: [[Pt^II^(en)~2~](μ-SCN)[Pt^IV^(en)~2~](μ-SCN)](ClO~4~)~4~ (en is ethane-1,2-diamine)
• Authors of publication: Ozawa, Yoshiki; Kim, Misa; Toriumi, Koshiro
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2013
• Journal volume: 69
• Journal issue: 2
• Pages of publication: 146 - 149
• a: 9.0535 ± 0.0013 Å
• b: 9.6033 ± 0.0014 Å
• c: 9.6034 ± 0.0014 Å
• α: 104.944 ± 0.004°
• β: 91.574 ± 0.004°
• γ: 113.765 ± 0.004°
• Cell volume: 730.11 ± 0.19 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0293
• Residual factor for significantly intense reflections: 0.0263
• Weighted residual factors for significantly intense reflections: 0.0698
• Weighted residual factors for all reflections included in the refinement: 0.0718
• Goodness-of-fit parameter for all reflections included in the refinement: 1.175
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes