Information card for entry 2018899

Structure parameters

• Chemical name: Tricarbonyl[9-(triphenylphosphonio)fluorenylidene]ruthenium
• Formula: C34 H21 O3 P Ru
• Calculated formula: C34 H21 O3 P Ru
• SMILES: [Ru]12(C#[O])(C#[O])(C#[O])C3([P+](c4ccccc4)(c4c1cccc4)c1c2cccc1)c1ccccc1c1c3cccc1
• Title of publication: Two complexes derived from the reaction of <i>M</i>~3~(CO)~12~ clusters (<i>M</i> = Ru, Os) with the 9-(triphenylphosphonio)fluorenide ylide: tricarbonyl[9-(triphenylphosphonio)fluorenylidene]ruthenium and nonacarbonyl-μ~3~-fluorenylidene-μ~2~-hydrido-<i>triangulo</i>-triosmium(III)
• Authors of publication: Arce, Alejandro; De Sanctis, Ysaura; Galarza, Esperanza; Garland, María Teresa; Baggio, Ricardo
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2013
• Journal volume: 69
• Journal issue: 4
• Pages of publication: 363 - 366
• a: 10.029 ± 0.007 Å
• b: 15.242 ± 0.005 Å
• c: 17.922 ± 0.005 Å
• α: 90°
• β: 93.5 ± 0.05°
• γ: 90°
• Cell volume: 2734 ± 2 ų
• Cell temperature: 295 ± 2 K
• Ambient diffraction temperature: 295 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1144
• Residual factor for significantly intense reflections: 0.0647
• Weighted residual factors for significantly intense reflections: 0.0709
• Weighted residual factors for all reflections included in the refinement: 0.0807
• Goodness-of-fit parameter for all reflections included in the refinement: 1.054
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes