Crystallography Open Database
- COD Home
- Accessing COD Data
- Add Your Data
- Documentation
Information card for entry 2020487
Preview
Coordinates | 2020487.cif |
---|---|
Structure factors | 2020487.hkl |
Original IUCr paper | HTML |
Common name | (PPh4)[V2(PS3'')2(mu-OMe)3] |
---|---|
Chemical name | Tetraphenylphosphonium tri-μ-methanolato-κ^6^<i>O</i>:<i>O</i>-bis({tris[2-sulfanidyl-3-(trimethylsilyl)phenyl]phosphane-κ^4^<i>P</i>,<i>S</i>,<i>S</i>',<i>S</i>''}vanadium(IV)) methanol disolvate |
Formula | C83 H109 O5 P3 S6 Si6 V2 |
Calculated formula | C83 H101 O5 P3 S6 Si6 V2 |
Title of publication | A non-oxo methanolate-bridged divanadium(IV) complex with tris(2-sulfanidylphenyl)phosphane ligands: synthesis, structural characterization and magnetic investigation |
Authors of publication | Wu, Hong-Ming; Chang, Ya-Ho; Su, Chia-Lin; Lee, Gene-Hsiang; Hsu, Hua-Fen |
Journal of publication | Acta Crystallographica Section C |
Year of publication | 2016 |
Journal volume | 72 |
Journal issue | 5 |
Pages of publication | 416 - 420 |
a | 18.474 ± 0.0012 Å |
b | 25.4633 ± 0.0018 Å |
c | 19.3663 ± 0.0013 Å |
α | 90° |
β | 100.036 ± 0.002° |
γ | 90° |
Cell volume | 8970.7 ± 1.1 Å3 |
Cell temperature | 150 ± 2 K |
Ambient diffraction temperature | 150 ± 2 K |
Number of distinct elements | 7 |
Space group number | 15 |
Hermann-Mauguin space group symbol | C 1 2/c 1 |
Hall space group symbol | -C 2yc |
Residual factor for all reflections | 0.1369 |
Residual factor for significantly intense reflections | 0.0877 |
Weighted residual factors for significantly intense reflections | 0.1712 |
Weighted residual factors for all reflections included in the refinement | 0.1912 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.097 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | Yes |
Has Fobs | Yes |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/2020487.html
All data in the COD and the database itself are dedicated to the
public domain and licensed under the
CC0
License
.
Users of the data should acknowledge the original authors of the
structural data.