Information card for entry 2020777

Structure parameters

• Chemical name: Bis(μ-diphenyl phosphato-κ^2^<i>O</i>:<i>O</i>')bis({<i>N</i>,<i>N</i>-bis[(pyridin-2-yl)methyl]quinolin-8-amine-κ^4^<i>N</i>,<i>N</i>',<i>N</i>'',<i>O</i>}cobalt(II)) bis(perchlorate)
• Formula: C66 H56 Cl2 Co2 N8 O16 P2
• Calculated formula: C66 H56 Cl2 Co2 N8 O16 P2
• SMILES: [Co]1234([O]=P(O[Co]567([O]=P(O1)(Oc1ccccc1)Oc1ccccc1)[n]1ccccc1C[N]5(Cc1[n]6cccc1)c1cccc5ccc[n]7c15)(Oc1ccccc1)Oc1ccccc1)[n]1ccccc1C[N]2(Cc1[n]3cccc1)c1cccc2ccc[n]4c12.Cl(=O)(=O)(=O)[O-].Cl(=O)(=O)(=O)[O-]
• Title of publication: Dinuclear cobalt(II) complexes with double phosphate ester bridges and tetradentate ligands having anisole or quinoline appendages
• Authors of publication: Anjana, S. S.; Varghese, Babu; Prasad, Edamana
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2017
• Journal volume: 73
• Journal issue: 6
• Pages of publication: 492 - 497
• a: 13.0021 ± 0.0002 Å
• b: 12.8075 ± 0.0003 Å
• c: 19.8373 ± 0.0004 Å
• α: 90°
• β: 93.008 ± 0.001°
• γ: 90°
• Cell volume: 3298.84 ± 0.11 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0526
• Residual factor for significantly intense reflections: 0.0414
• Weighted residual factors for significantly intense reflections: 0.1027
• Weighted residual factors for all reflections included in the refinement: 0.1092
• Goodness-of-fit parameter for all reflections included in the refinement: 1.088
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes