Information card for entry 2022414

Structure parameters

• Chemical name: (μ~6~-Aqua)(μ~3~-propan-2-ol)pentakis(μ~3~-triphenylsilanolato)(μ~2~-triphenylsilanolato)hexapotassium toluene disolvate
• Formula: C125 H116 K6 O8 Si6
• Calculated formula: C125 H116 K6 O8 Si6
• Title of publication: Polyoxometalate-like structure of new potassium triphenylsiloxides: [K~6~(OSiPh~3~)~6~(C~3~H~7~OH)(H~2~O)]·2C~6~H~5~CH~3~ and [K~6~(OSiPh~3~)~6~(H~2~O)~2~]
• Authors of publication: Wytrych, Patrycja; Utko, Józef; Lis, Tadeusz; John, Łukasz
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2021
• Journal volume: 77
• Journal issue: 9
• a: 13.081 ± 0.002 Å
• b: 14.96 ± 0.003 Å
• c: 31.017 ± 0.004 Å
• α: 82.52 ± 0.02°
• β: 87.24 ± 0.02°
• γ: 69.51 ± 0.02°
• Cell volume: 5637.4 ± 1.8 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.09
• Residual factor for significantly intense reflections: 0.0766
• Weighted residual factors for significantly intense reflections: 0.2122
• Weighted residual factors for all reflections included in the refinement: 0.2207
• Goodness-of-fit parameter for all reflections included in the refinement: 1.103
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: Yes