Information card for entry 2023132

Structure parameters

• Chemical name: Bis(4,4-dimethyl-2-phenyl-2-oxazoline-κ<i>N</i>)(hexamethyldisilylamido-κ<i>N</i>)lithium
• Formula: C28 H44 Li N3 O2 Si2
• Calculated formula: C28 H44 Li N3 O2 Si2
• Title of publication: Crystal structure of a three-coordinate lithium complex with monodentate phenyloxazoline and hexamethyldisilylamide ligands
• Authors of publication: Carneiro Neto, José Severiano; Iwaya, Eduardo Mariano; Santana, Francielli Sousa; Soares, Jaísa Fernandes
• Journal of publication: Acta Crystallographica Section E Crystallographic Communications
• Year of publication: 2024
• Journal volume: 80
• Journal issue: 6
• a: 15.612 ± 0.002 Å
• b: 12.7649 ± 0.0017 Å
• c: 17.18 ± 0.004 Å
• α: 90°
• β: 116.243 ± 0.005°
• γ: 90°
• Cell volume: 3070.8 ± 0.9 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0492
• Residual factor for significantly intense reflections: 0.0352
• Weighted residual factors for significantly intense reflections: 0.0865
• Weighted residual factors for all reflections included in the refinement: 0.0915
• Goodness-of-fit parameter for all reflections included in the refinement: 1.039
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No