Information card for entry 2100995

Structure parameters

• Formula: C50 H39 Ir N3 O P2
• Calculated formula: C56 H30 Ir N3 O P2
• Title of publication: Structure of <i>trans</i>-<i>M</i>(CO)(C~4~N~3~)(PPh~3~)~2~.1.5C~6~H~6~ (<i>M</i> = Ir and Rh): the pyramidal geometry of the tricyanomethanide anion (C~4~N~3~^{-^})
• Authors of publication: Wang, J.-C.; Shih, L. J.; Chen, Y.-J.; Wang, Y.; Fronczek, F. R.; Watkins, S. F.
• Journal of publication: Acta Crystallographica Section B
• Year of publication: 1993
• Journal volume: 49
• Journal issue: 4
• Pages of publication: 680 - 685
• a: 11.549 ± 0.003 Å
• b: 12.528 ± 0.002 Å
• c: 16.931 ± 0.002 Å
• α: 91.13 ± 0.01°
• β: 99.45 ± 0.02°
• γ: 114.87 ± 0.02°
• Cell volume: 2181.5 ± 0.8 ų
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: Mo
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No