Information card for entry 2201463

Structure parameters

• Chemical name: Bis[μ-bis(diphenylphosphino)amine-κP:P']bis[acetonitrilesiliver(I)] tris(cis-1,2-dicyanoethylene 1,2-dithiolate)molybdenate(IV)
• Formula: C64 H48 Ag2 Mo N10 P4 S6
• Calculated formula: C64 H48 Ag2 Mo N10 P4 S6
• SMILES: N1[P]([Ag]2([N]#CC)[Ag]([P]1(c1ccccc1)c1ccccc1)([N]#CC)[P](N[P]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1.[Mo]123(SC(C#N)=C(S1)C#N)(SC(=C(S2)C#N)C#N)SC(C#N)=C(S3)C#N
• Title of publication: Bis[μ-bis(diphenylphosphino)amine-κ<i>P</i>:<i>P</i>']bis[acetonitrilesilver(I)] tris(<i>cis</i>-1,2-dicyanoethylene-1,2-dithiolate)molybdate(IV)
• Authors of publication: Xu, Hong-Wu; Chen, Zhong-Ning; Wu, Ji-Gui
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2002
• Journal volume: 58
• Journal issue: 11
• Pages of publication: m631 - m633
• a: 17.181 ± 0.003 Å
• b: 15.313 ± 0.003 Å
• c: 26.386 ± 0.005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 6942 ± 2 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 60
• Hermann-Mauguin space group symbol: P b c n
• Hall space group symbol: -P 2n 2ab
• Residual factor for all reflections: 0.1322
• Residual factor for significantly intense reflections: 0.063
• Weighted residual factors for significantly intense reflections: 0.1092
• Weighted residual factors for all reflections included in the refinement: 0.135
• Goodness-of-fit parameter for all reflections included in the refinement: 1.165
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes