Information card for entry 2201634

Structure parameters

• Chemical name: Bis[μ-bis(diphenylphosphino)methane-κ^2^P:P']bis[(saccharinato- κN)palladium(I)] dichloromethane solvate
• Formula: C65 H54 Cl2 N2 O6 P4 Pd2 S2
• Calculated formula: C65 H54 Cl2 N2 O6 P4 Pd2 S2
• SMILES: [Pd]12([Pd]([P](C[P]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)([P](C[P]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)N1S(=O)(=O)c2c(C1=O)cccc2)N1S(=O)(=O)c2c(C1=O)cccc2.ClCCl
• Title of publication: Bis[μ-bis(diphenylphosphino)methane-κ^2^<i>P</i>:<i>P</i>']bis[(saccharinato-κ<i>N</i>)palladium(I)] dichloromethane solvate
• Authors of publication: Henderson, William; Nicholson, Brian K.; Chung, Dong C.
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2002
• Journal volume: 58
• Journal issue: 8
• Pages of publication: m432 - m433
• a: 13.819 ± 0.004 Å
• b: 22.55 ± 0.007 Å
• c: 20.23 ± 0.006 Å
• α: 90°
• β: 108.53 ± 0.01°
• γ: 90°
• Cell volume: 5977 ± 3 ų
• Cell temperature: 168 ± 2 K
• Ambient diffraction temperature: 168 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.031
• Residual factor for significantly intense reflections: 0.025
• Weighted residual factors for significantly intense reflections: 0.065
• Weighted residual factors for all reflections included in the refinement: 0.068
• Goodness-of-fit parameter for all reflections included in the refinement: 1.02
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes