Information card for entry 2201893

Structure parameters

• Chemical name: Bis[μ-methylenebis(diphenylphosphine)-P:P']disilver(I) diperchlorate diacetonitrile solvate
• Formula: C54 H50 Ag2 Cl2 N2 O8 P4
• Calculated formula: C54 H50 Ag2 Cl2 N2 O8 P4
• SMILES: CC#N.[P]1(c2ccccc2)(c2ccccc2)[Ag][P](c2ccccc2)(c2ccccc2)C[P](c2ccccc2)(c2ccccc2)[Ag][P](C1)(c1ccccc1)c1ccccc1.Cl(=O)(=O)(=O)[O-].CC#N.Cl(=O)(=O)(=O)[O-]
• Title of publication: Bis[μ-methylenebis(diphenylphosphine)-κ^2^<i>P</i>:<i>P</i>']disilver(I) diperchlorate acetonitrile disolvate
• Authors of publication: Wei, Qiaohua; Yin, Gangqiang; Chen, Zhongning
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2003
• Journal volume: 59
• Journal issue: 5
• Pages of publication: m232 - m233
• a: 11.4553 ± 0.0003 Å
• b: 15.1766 ± 0.0001 Å
• c: 16.0597 ± 0.0005 Å
• α: 90°
• β: 101.826 ± 0.002°
• γ: 90°
• Cell volume: 2732.76 ± 0.11 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1351
• Residual factor for significantly intense reflections: 0.0664
• Weighted residual factors for significantly intense reflections: 0.1044
• Weighted residual factors for all reflections included in the refinement: 0.1314
• Goodness-of-fit parameter for all reflections included in the refinement: 1.143
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes