Information card for entry 2204173

Structure parameters

• Chemical name: poly[[tetrakis(N,N'dimethylformamide)pentacopper(I,II)]-tetra-μ~2~-cyano- di-μ~3~-cyano]
• Formula: C18 H28 Cu5 N10 O4
• Calculated formula: C18 H28 Cu5 N10 O4
• Title of publication: [Cu~4~^I^Cu^II^(CN)~6~(DMF)~4~]~<i>n~</i> (DMF is <i>N</i>,<i>N</i>'-dimethylformamide): redetermination and topological analysis of a mixed-valence copper‒cyanide coordination polymer with a unique six-connected self-penetrating network
• Authors of publication: Xiao-Jun Zhao; Stuart R Batten; Miao Du
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2004
• Journal volume: 60
• Journal issue: 9
• Pages of publication: m1237 - m1239
• a: 14.054 ± 0.004 Å
• b: 12.597 ± 0.004 Å
• c: 16.424 ± 0.005 Å
• α: 90°
• β: 92.008 ± 0.006°
• γ: 90°
• Cell volume: 2905.9 ± 1.5 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.1028
• Residual factor for significantly intense reflections: 0.0482
• Weighted residual factors for significantly intense reflections: 0.0789
• Weighted residual factors for all reflections included in the refinement: 0.0918
• Goodness-of-fit parameter for all reflections included in the refinement: 0.974
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes