Information card for entry 2205978

Structure parameters

• Chemical name: bis[(+)-(1R,4R)-3-(trifluoroacetyl)camphorato- κ^2^O,O'][bis(trimethylsilyl)amido-κN](1,3,5-trimethyl-1,3,5- triazacyclohexane-κ^3^N,N',N'')cerium(III)
• Formula: C36 H61 Ce F6 N4 O4 Si2
• Calculated formula: C36 H61 Ce F6 N4 O4 Si2
• Title of publication: An optically active heteroleptic cerium camphorate: [bis(trimethylsilyl)amido-κ<i>N</i>]bis[(+)-(1<i>R</i>,4<i>R</i>)-3-(trifluoroacetyl)camphorato-κ^2^<i>O</i>,<i>O</i>'](1,3,5-trimethyl-1,3,5-triazacyclohexane-κ^3^<i>N</i>,<i>N</i>',<i>N</i>'')cerium(III)
• Authors of publication: Niemeyer, Mark; Cristoffers, Jens; Michael Rössle
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2005
• Journal volume: 61
• Journal issue: 6
• Pages of publication: m1207 - m1209
• a: 10.17 ± 0.003 Å
• b: 14.934 ± 0.004 Å
• c: 29.568 ± 0.008 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4491 ± 2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.053
• Residual factor for significantly intense reflections: 0.041
• Weighted residual factors for significantly intense reflections: 0.097
• Weighted residual factors for all reflections included in the refinement: 0.103
• Goodness-of-fit parameter for all reflections included in the refinement: 1.47
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: Yes