Information card for entry 2207632

Structure parameters

• Chemical name: [Bis(diphenylphosphino)methane-κ^2^P,P'][bis(diphenylthiophosphinyl)methane- κ^2^S,S']platinum(II) bis(perchlorate) acetone solvate
• Formula: C53 H50 Cl2 O9 P4 Pt S2
• Calculated formula: C53 H50 Cl2 O9 P4 Pt S2
• SMILES: CC(=O)C.[Pt]12([S]=P(CP(=[S]1)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)[P](C[P]2(c2ccccc2)c2ccccc2)(c1ccccc1)c1ccccc1.Cl(=O)(=O)(=O)[O-].Cl(=O)(=O)(=O)[O-]
• Title of publication: [Bis(diphenylphosphino)methane-κ^2^<i>P</i>,<i>P</i>'][bis(diphenylthiophosphinyl)methane-κ^2^<i>S</i>,<i>S</i>']platinum(II) bis(perchlorate) acetone solvate
• Authors of publication: Alkan, Leman; İrişli, Sevil
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2005
• Journal volume: 61
• Journal issue: 12
• Pages of publication: m2706 - m2708
• a: 20.888 ± 0.002 Å
• b: 11.8633 ± 0.0014 Å
• c: 23.109 ± 0.003 Å
• α: 90°
• β: 107.686 ± 0.002°
• γ: 90°
• Cell volume: 5455.8 ± 1.1 ų
• Cell temperature: 297 ± 2 K
• Ambient diffraction temperature: 297 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0834
• Residual factor for significantly intense reflections: 0.0763
• Weighted residual factors for significantly intense reflections: 0.1584
• Weighted residual factors for all reflections included in the refinement: 0.1616
• Goodness-of-fit parameter for all reflections included in the refinement: 1.255
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes