Information card for entry 2209603

Structure parameters

• Chemical name: [μ~2~-bis(2,6-diisopropylphenylamido)phenylphosphine]bis(diethyl ether)dilithium(I)
• Formula: C38 H59 Li2 N2 O2 P
• Calculated formula: C38 H59 Li2 N2 O2 P
• SMILES: P1([N]2([Li]([N]1([Li]2[O](CC)CC)c1c(cccc1C(C)C)C(C)C)[O](CC)CC)c1c(cccc1C(C)C)C(C)C)c1ccccc1
• Title of publication: A monomeric <i>N</i>,<i>N</i>'-dilithiobis(amido)organophosphane
• Authors of publication: Copsey, May C.; Chivers, Tristram
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2006
• Journal volume: 62
• Journal issue: 7
• Pages of publication: m1560 - m1561
• a: 15.679 ± 0.003 Å
• b: 15.381 ± 0.003 Å
• c: 16.734 ± 0.003 Å
• α: 90°
• β: 109.78 ± 0.03°
• γ: 90°
• Cell volume: 3797.4 ± 1.4 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0889
• Residual factor for significantly intense reflections: 0.0499
• Weighted residual factors for significantly intense reflections: 0.106
• Weighted residual factors for all reflections included in the refinement: 0.1228
• Goodness-of-fit parameter for all reflections included in the refinement: 1.025
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes