Information card for entry 2209962

Structure parameters

• Chemical name: <i>cis</i>-Bis[diphenyl(phenylsulfanylmethyl)diphenylphosphine- κP]bis(pentafluorophenyl)gold(III) perchlorate chloroform solvate
• Formula: C51 H35 Au Cl4 F10 O4 P2 S2
• Calculated formula: C51 H35 Au Cl4 F10 O4 P2 S2
• SMILES: [Au]([P](CSc1ccccc1)(c1ccccc1)c1ccccc1)([P](CSc1ccccc1)(c1ccccc1)c1ccccc1)(c1c(c(c(c(c1F)F)F)F)F)c1c(c(c(c(c1F)F)F)F)F.Cl(=O)(=O)(=O)[O-].C(Cl)(Cl)Cl
• Title of publication: <i>cis</i>-Bis[diphenyl(phenylsulfanylmethyl)diphenylphosphine-κ<i>P</i>]bis(pentafluorophenyl)gold(III) perchlorate chloroform solvate
• Authors of publication: Jones, Peter G.; Fernández, Eduardo J.; López-de-Luzuriaga, José M.; Monge, Miguel; Laguna, Antonio
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2006
• Journal volume: 62
• Journal issue: 8
• Pages of publication: m1997 - m1999
• a: 11.29 ± 0.002 Å
• b: 13.795 ± 0.002 Å
• c: 34.421 ± 0.004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 5360.9 ± 1.4 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 8
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0559
• Residual factor for significantly intense reflections: 0.0373
• Weighted residual factors for significantly intense reflections: 0.0657
• Weighted residual factors for all reflections included in the refinement: 0.0692
• Goodness-of-fit parameter for all reflections included in the refinement: 0.92
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes