Information card for entry 2211934

Structure parameters

• Chemical name: bis(μ-benzene-1,2-dithiolato)bis[(2- mercaptobenzenethiolato)triphenylphosphine)rhodium(III)] dichloromethane tetrasolvate
• Formula: C64 H56 Cl8 P2 Rh2 S8
• Calculated formula: C64 H56 Cl8 P2 Rh2 S8
• SMILES: c12ccccc1[SH][Rh]13([P](c4ccccc4)(c4ccccc4)c4ccccc4)(S2)Sc2ccccc2[S]1[Rh]12([P](c4ccccc4)(c4ccccc4)c4ccccc4)(Sc4ccccc4[SH]1)Sc1ccccc1[S]32.C(Cl)Cl.C(Cl)Cl.C(Cl)Cl.C(Cl)Cl
• Title of publication: A bis(benzenedithiolate)-bridged dinuclear Rh^III^ complex with capping triphenylphosphine ligands and an Rh~2~S~2~ core
• Authors of publication: Hadebe, Siphamandla W.; Robinson, Ross R.; Munro, Orde Q.
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2007
• Journal volume: 63
• Journal issue: 1
• Pages of publication: m175 - m177
• a: 10.8719 ± 0.0005 Å
• b: 11.0495 ± 0.0005 Å
• c: 14.2621 ± 0.0005 Å
• α: 104.781 ± 0.004°
• β: 97.789 ± 0.004°
• γ: 96.089 ± 0.004°
• Cell volume: 1623.53 ± 0.13 ų
• Cell temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.0247
• Weighted residual factors for all reflections included in the refinement: 0.06
• Goodness-of-fit parameter for all reflections included in the refinement: 1.082
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes